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Creators/Authors contains: "Materon, Luis"

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  1. Graphene and graphene oxide have shown good antibacterial activity against different bacterial species due to their unique physicochemical properties. Graphene oxide (GO) has been widely used to load metallic and metal oxide nanoparticles (NPs) to minimize their surface energy during processing and preparation, hence reducing their aggregation. In this work, GO was effectively synthesized and coated with different concentrations of zinc hydroxide Zn (OH)x using the precipitation method to prepare a GO/Zn (OH)x hybrid composite. The Zn (OH)x NPs and GO/Zn (OH)x nanocomposites were synthesized and characterized using various methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Coating GO with Zn (OH)x NPs resulted in improved aggregation of Zn (OH)x NPs as well as enhanced antibacterial activity of GO against Gram-positive and Gram-negative bacteria. Additionally, the effect of Zn (OH)x coating on the antibacterial properties of the GO/Zn (OH)x composite was systematically investigated. The synergistic effects of GO and Zn (OH)x NPs resulted in enhanced antibacterial properties of the composites compared to the pristine GO material. In addition, increasing the Zn (OH)x wt. % concentration led to an increased inhibition zone of the GO/Zn (H)x composite against Bacillus megaterium and E. coli bacteria. 
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  2. Abstract Polyvinylpyrrolidone (PVP) fibers embedded with Zinc Oxide nanoparticles (ZnO NPs) were prepared by the centrifugal spinning of aqueous PVP solutions and ZnO NPs. The ZnO NPs were synthesized and coated with either cetyltrimethylammonium bromide or hexadecyltrimethylammonium bromide. The structure and morphology of the nanocomposite fibers were studied using scanning electron microscopy, X‐ray diffraction, energy‐dispersive X‐ray spectroscopy, Fourier transformed infrared spectroscopy and Thermogravimetric analysis. The effect of surfactant coating on the antibacterial activity of ZnO NPs and PVP/ZnO nanocomposite fibers againstEscherichia coli(E. coli) andBacillus megaterium(B. megaterium) bacteria was systematically investigated. The present study indicated that coating the ZnO NPs with surfactants resulted in large and uniform inhibition of bacterial growth. 
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  3. Abstract Copper nanoparticles (CuNPs) embedded in polyvinylpyrrolidone (PVP) and polyethylene oxide (PEO) fiber‐matrices were prepared through centrifugal spinning of PVP/ethanol and PEO/aqueous solutions, respectively. The prime focus of the current study is to investigate the antibacterial activity of composite fibers againstEscherichia coli(E. coli) andBacillus cereus(B. cereus) bacteria. During the fiber formation, the centrifugal spinning parameters such as spinneret rotational speed, spinneret to collector distance, and relative humidity were carefully chosen to obtain long and continuous fibers. The structural and morphological analyses of both composite fibers were investigated using scanning electron microscopy, X‐ray diffraction, energy‐dispersive X‐ray spectroscopy, and thermogravimetric analysis. In the antibacterial test, PVP/Cu and PEO/Cu composite fibrous membranes exhibited inhibition efficiency of 99.98% and 99.99% againstE. coliandB. cereusbacteria, respectively. Basically, CuNPs were well embedded in the fibrous membrane at the nanoscale level, which facilitated the inhibition of bacterial functions through the inactivation of the chemical structure of the cells. Such an effective antibacterial agent obtained from forcespun composite fibers could be promising candidates for biomedical applications. 
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